By Vladimir M. Gun'ko,Vladimir V. Turov
Properties and functions of excessive floor zone fabrics rely on interfacial phenomena, together with diffusion, sorption, dissolution, solvation, floor reactions, catalysis, and section transitions. one of the physicochemical equipment that provide worthy information about those advanced phenomena, nuclear magnetic resonance (NMR) spectroscopy is the main common, yielding unique structural info concerning molecules, solids, and interfaces. Nuclear Magnetic Resonance stories of Interfacial Phenomena summarizes NMR examine effects amassed during the last 3 a long time for quite a lot of materials—from nanomaterials and nanocomposites to biomaterials, cells, tissues, and seeds.
This publication describes the purposes of vital new NMR spectroscopic easy methods to numerous worthy fabrics and compares them with effects from different thoughts corresponding to adsorption, differential scanning calorimetry, thermally prompted depolarization present, dielectric rest spectroscopy, infrared spectroscopy, optical microscopy, and small-angle and wide-angle x-ray scattering. The textual content explores the appliance of NMR spectroscopy to envision interfacial phenomena in items of accelerating complexity, starting with unmodified and transformed silica fabrics. It then describes homes of varied combined oxides with comparisons to person oxides and likewise describes carbon fabrics reminiscent of graphite and carbon nanotubes.
Chapters take care of carbon–mineral hybrids and their mosaic floor buildings, and interfacial phenomena on the floor of ordinary and synthetics polymers. additionally they discover quite a few biosystems, that are even more advanced, together with biomacromolecules (proteins, DNA, and lipids), cells and tissues, and seeds and herbs. The authors hide developments in interfacial phenomena investigations, and the ultimate bankruptcy describes NMR and different tools utilized in the ebook. this article offers a accomplished description of a giant array of tough and delicate fabrics, permitting the research of the structure–property relationships and generalities at the interfacial habit of fabrics and adsorbates.
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